The Hall effect and the conduction electron density in Ni-based amorphous alloys
J Ivkov; E Babic; H H Liebermann; J Ivkov; Inst. of Phys., Zagreb Univ., Yugoslavia; E Babic; Inst. of Phys., Zagreb Univ., Yugoslavia; H H Liebermann; Inst. of Phys., Zagreb Univ., Yugoslavia
Журнал:
Journal of Physics: Condensed Matter
Дата:
1990-10-29
Аннотация:
New results for the normal Hall coefficient R<sub>0</sub>, the resistivity and the room-temperature coefficient of resistivity of five Ni-Bi-Si and six Ni-P amorphous (melt-quenched) alloys are reported. From these results, and results already reported, the authors have obtained rather detailed information on the variation in the conduction electron density with the metalloid concentration c<sub>m</sub> in the amorphous Ni-B-Si alloys. The results for the alloys with low c<sub>m</sub> extrapolate to those of liquid Ni, whereas the variation in the Fermi wavevector (deduced from R<sub>0</sub>) with c<sub>m</sub> supports the applicability of the Ziman-Faber theory for the explanation of the transport properties of these alloys. The contribution of the metalloid atoms to the conduction band is found to change at c<sub>m</sub> approximately=0.3, which is probably related to filling of the d band. This change occurs in the range of c<sub>m</sub> in which a significant change in the chemical short-range order has been observed. Although less detailed, the results for the Ni-P alloys follow the same trend as those for Ni-B-Si alloys and do not indicate any dramatic change in R<sub>0</sub> at around c<sub>m</sub> approximately=0.24 as reported for electrodeposited Ni-P alloys.
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