Order and disorder processes in the Raman spectrum of KTa<sub>1-x</sub>Nb<sub>x</sub>O<sub>3</sub>
M D Fontana; E Bouziane; G E Kugel; M D Fontana; Centre Lorrain d'Opti. et Electron. des Solides, Univ., de Metz et Supelec, France; E Bouziane; Centre Lorrain d'Opti. et Electron. des Solides, Univ., de Metz et Supelec, France; G E Kugel; Centre Lorrain d'Opti. et Electron. des Solides, Univ., de Metz et Supelec, France
Журнал:
Journal of Physics: Condensed Matter
Дата:
1990-10-29
Аннотация:
The authors present light scattering measurements up to 800 cm<sup>-1</sup> for KTa<sub>1-x</sub>Nb<sub>x</sub>O<sub>3</sub> crystals with high niobium (9 at.%) and low niobium (2 at.%) concentrations. The spectra in the ordered cubic phase (at high temperatures) and rhombohedral phase (at low temperatures) are characterised by normal second- and first-order lines, respectively, as required by symmetry. Nevertheless, in the cubic phase, within a temperature range depending on the niobium concentration, the spectrum exhibits a broad central peak and lines activated by local symmetry breaking. This intermediate state can be defined as a precursor ferroelectric ordering state above T<sub>c</sub>. The continuous change in the Raman spectrum with decreasing temperature can therefore be attributed to a gradual dipolar clustering process induced by relaxing Nb ions in the KTaO<sub>3</sub> lattice.
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