A theory of non-linear stretch vibrations of hydrogen bonds
Wen-Ge Han; Chun-Ting Zhang; Wen-Ge Han; Dept. of Phys., Tianjin Univ., China; Chun-Ting Zhang; Dept. of Phys., Tianjin Univ., China
Журнал:
Journal of Physics: Condensed Matter
Дата:
1991-01-07
Аннотация:
A non-linear vibration of the stretch of hydrogen bonds has been studied theoretically. The authors have used the potential V(r)=Ar<sup>2</sup>-Br<sup>3</sup>, where A and B are constants, to describe approximately the H-bond energy. They have obtained analytical solutions of the motion equation for a particle moving in this potential field. The theoretical results have been applied to some realistic physics systems, including water molecules, the DNA double helix and the alpha -helix protein. It is shown that the calculated vibration frequencies are in agreement with experimental data observed by the Raman scattering and other techniques. The asymmetry of the H-bond energy is also discussed.
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