Synthesis and characterization of Y-Ba-Cu-O and Bi(Pb)-Sr-Ca-Cu-O superconductors from the oxine co-precipitation method
G K Padam; V Raman; Indu Dhingra; R B Tripathi; S U M Rao; D K Suri; K C Nagpal; B K Das; G K Padam; Nat. Phys. Lab., New Delhi, India; V Raman; Nat. Phys. Lab., New Delhi, India; Indu Dhingra; Nat. Phys. Lab., New Delhi, India; R B Tripathi; Nat. Phys. Lab., New Delhi, India; S U M Rao; Nat. Phys. Lab., New Delhi, India; D K Suri; Nat. Phys. Lab., New Delhi, India; K C Nagpal; Nat. Phys. Lab., New Delhi, India; B K Das; Nat. Phys. Lab., New Delhi, India
Журнал:
Journal of Physics: Condensed Matter
Дата:
1991-06-10
Аннотация:
Oxide superconductors in the Y-Ba-Cu-O and Bi(Pb)-Sr-Ca-Cu-O systems with T<sub>c</sub> degrees of 93.6 K and 115 K, respectively, have been prepared by the co-precipitation process via the oxine route using nitrates as the starting materials. Chemical homogeneity, stoichiometry and fine particles of the precursor obtained by this process permit a relatively short time for the production of Y- and Bi-based superconducting compounds compared with that obtained by the conventional solid state reaction method. The resulting densities of the sintered samples were typically greater than 90%. X-ray diffraction analysis, energy dispersive spectral analysis and scanning electron microstructural analysis are also reported in this study.
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