The ferroelectric phase transition in pure and lightly doped barium titanate
C N W Darlington; R J Cernik; C N W Darlington; Sch. of Phys. & Space Res., Birmingham Univ., UK; R J Cernik; Sch. of Phys. & Space Res., Birmingham Univ., UK
Журнал:
Journal of Physics: Condensed Matter
Дата:
1991-06-24
Аннотация:
The effect of light doping on the phase transition to the ferroelectric state in BaTiO<sub>3</sub> has been studied using synchrotron radiation at Daresbury Laboratory, UK. The results indicate that the presence of dilute impurities, which turn BaTiO<sub>3</sub> from a wide band-gap intrinsic semiconductor into an extrinsic n-type semiconductor, changes the transition from a discontinuous to a continuous one, and produces large spatial variation in magnitude of the electric polarization in both the high- and low-temperature phases; these fluctuations were barely detectable in the pure, annealed material.
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