| Автор | E Salomons |
| Автор | M Mareschal |
| Дата выпуска | 1991-11-18 |
| dc.description | Liquid-vapour coexistence and surface tension of binary mixtures is studied by Monte Carlo simulation. Both mixtures with a difference in the size parameters and mixtures with a difference in the energy parameters of the Lennard-Jones potential are investigated. The results for the surface tension and the coexisting liquid density are compared with the predictions of one-fluid models. The van der Waals model is found to be quite accurate, except in cases of strong interfacial adsorption. An interpretation of this accuracy is given, by developing a one-fluid model based on random packing of hard spheres. It is found that the predictions of this random-packing model are close to predictions of the van der Waals one-fluid model. The authors also present a simulation of the argon-krypton liquid-vapour interface. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | Atomistic simulation of liquid-vapour coexistence: binary mixtures |
| Тип | paper |
| DOI | 10.1088/0953-8984/3/46/021 |
| Electronic ISSN | 1361-648X |
| Print ISSN | 0953-8984 |
| Журнал | Journal of Physics: Condensed Matter |
| Том | 3 |
| Первая страница | 9215 |
| Последняя страница | 9228 |
| Аффилиация | E Salomons; CEREM-DTM-SRMP, CENS, Gif-sur-Yvette, France |
| Аффилиация | M Mareschal; CEREM-DTM-SRMP, CENS, Gif-sur-Yvette, France |
| Выпуск | 46 |
