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Автор K R Lykke
Автор B D Kay
Дата выпуска 1991-11-01
dc.description Resonantly enhanced multi-photon ionization (REMPI) laser spectroscopic and molecular beam-surface scattering techniques are coupled to study the rotationally inelastic scattering of N<sub>2</sub> from Au(111). The scattered N<sub>2</sub> rotational distributions are markedly non-Boltzmann and exhibit pronounced maxima at large angular momentum transfers ( Delta J=20 to 30). These maxima are indicative of direct rotational rainbow scattering and strongly depend upon the translational energy of the incident N<sub>2</sub> molecular beam. The translational energy dependence of the rainbow rotational energy yeilds a value of 4.1 kcal mol<sup>-1</sup> for the depth of the laterally averaged N<sub>2</sub>-Au(111) physisorption potential.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Rotational rainbows in the inelastic scattering of N<sub>2</sub> from Au(111)
Тип paper
DOI 10.1088/0953-8984/3/S/010
Electronic ISSN 1361-648X
Print ISSN 0953-8984
Журнал Journal of Physics: Condensed Matter
Том 3
Первая страница S65
Последняя страница S70
Аффилиация K R Lykke; Sandia Nat. Labs., Albuquerque, NM, USA
Аффилиация B D Kay; Sandia Nat. Labs., Albuquerque, NM, USA
Выпуск S

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