Автор |
K R Lykke |
Автор |
B D Kay |
Дата выпуска |
1991-11-01 |
dc.description |
Resonantly enhanced multi-photon ionization (REMPI) laser spectroscopic and molecular beam-surface scattering techniques are coupled to study the rotationally inelastic scattering of N<sub>2</sub> from Au(111). The scattered N<sub>2</sub> rotational distributions are markedly non-Boltzmann and exhibit pronounced maxima at large angular momentum transfers ( Delta J=20 to 30). These maxima are indicative of direct rotational rainbow scattering and strongly depend upon the translational energy of the incident N<sub>2</sub> molecular beam. The translational energy dependence of the rainbow rotational energy yeilds a value of 4.1 kcal mol<sup>-1</sup> for the depth of the laterally averaged N<sub>2</sub>-Au(111) physisorption potential. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Название |
Rotational rainbows in the inelastic scattering of N<sub>2</sub> from Au(111) |
Тип |
paper |
DOI |
10.1088/0953-8984/3/S/010 |
Electronic ISSN |
1361-648X |
Print ISSN |
0953-8984 |
Журнал |
Journal of Physics: Condensed Matter |
Том |
3 |
Первая страница |
S65 |
Последняя страница |
S70 |
Аффилиация |
K R Lykke; Sandia Nat. Labs., Albuquerque, NM, USA |
Аффилиация |
B D Kay; Sandia Nat. Labs., Albuquerque, NM, USA |
Выпуск |
S |