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Автор F K Koschnick
Автор J -M Spaeth
Автор R S Eachus
Дата выпуска 1992-03-16
dc.description Using magneto-optical and optically detected electron paramagnetic resonance methods, it is shown that in BaFBr single crystals grown using standard procedures the ubiquitous oxide impurity is primarily responsible for the X-irradiation-induced formation of F(Br<sup>-</sup>) centres. The bromide vacancy formed to charge compensate O<sup>2-</sup> is implicated in the direct trapping of electrons. F(F<sup>-</sup>) centres are also produced by irradiation, probably by an exciton collapse process requiring thermal activation. Cross relaxation measurements show that many of the F(F<sup>-</sup>) and F(Br<sup>-</sup>) centres are spatially correlated, more than expected on statistical grounds. The relevance of these results to the use of rare earth-activated BaFBr materials as storage phosphors is discussed.
Формат application.pdf
Издатель Institute of Physics Publishing
Название The influence of oxide impurity on the generation by X-irradiation of F centres in BaFBr
Тип paper
DOI 10.1088/0953-8984/4/11/025
Electronic ISSN 1361-648X
Print ISSN 0953-8984
Журнал Journal of Physics: Condensed Matter
Том 4
Первая страница 3015
Последняя страница 3029
Аффилиация F K Koschnick; Paderborn Univ., Germany
Аффилиация J -M Spaeth; Paderborn Univ., Germany
Аффилиация R S Eachus; Paderborn Univ., Germany
Выпуск 11

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