Magnetic characterization and structural study of new ternary carbides: ThFe<sub>11</sub>C<sub>x</sub> (1.5<or=x<or=2)
O Isnard; J L Soubeyroux; D Fruchart; T H Jacobs; K H J Buschow; O Isnard; Inst. Laue-Langevin, Grenoble, France; J L Soubeyroux; Inst. Laue-Langevin, Grenoble, France; D Fruchart; Inst. Laue-Langevin, Grenoble, France; T H Jacobs; Inst. Laue-Langevin, Grenoble, France; K H J Buschow; Inst. Laue-Langevin, Grenoble, France
Журнал:
Journal of Physics: Condensed Matter
Дата:
1992-07-27
Аннотация:
The authors report on the crystal and magnetic structure determination of ThFe<sub>11</sub>C<sub>x</sub>. The positions of the metal atoms correspond to the BaCd<sub>11</sub> type of structure. The carbon atoms occupy octahedral sites formed by four iron and two thorium atoms. Compounds having carbon concentrations x=1.5 and 2 were found in order magnetically between 400 and 500 K. Low-temperature neutron diffraction experiments provide evidence of a ferromagnetic structure with moments oriented perpendicular to the c axis whereas at room temperature the magnetic moments appear to be aligned parallel to the c axis of the tetragonal structure.
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