Structural changes in silver bromide at the melting point
V M Nield; D A Keen; W Hayes; R L McGreevy; V M Nield; Clarendon Lab., Oxford, UK; D A Keen; Clarendon Lab., Oxford, UK; W Hayes; Clarendon Lab., Oxford, UK; R L McGreevy; Clarendon Lab., Oxford, UK
Журнал:
Journal of Physics: Condensed Matter
Дата:
1992-08-10
Аннотация:
A neutron diffraction study has been performed on AgBr at a series of temperatures from 293 K to 706 K (melting point, T<sub>m</sub>=701 K), including measurements as close as 0.3+or-0.05 degrees from T<sub>m</sub>. Analysis of the structure factors using the reverse Monte Carlo modelling technique indicates that the motion of the Ag<sup>+</sup> ions about their rocksalt lattice sites is anisotropic, with increasing occupancy of the (1/4 1/4 1/4) tetrahedral interstitial site as the melting point is approached. It is concluded that the silver sub-lattice is undergoing a second-order transition to a fast-ion phase in which both tetrahedral and octahedral sites are occupied (possibly similar to the fast-ion transition in the high pressure FCC phase of AgI) although melting prevents complete transition. There is a clear discontinuity in Bragg scattering at T<sub>m</sub>, suggesting that the first-order nature of the melting transition is unaffected.
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