Pressure-induced valence changes in mixed-valent systems
L Chandran; H R Krishna-murthy; T V Ramakrishnan; L Chandran; Dept. of Phys., Indian Inst. of Sci., Bangalore, India; H R Krishna-murthy; Dept. of Phys., Indian Inst. of Sci., Bangalore, India; T V Ramakrishnan; Dept. of Phys., Indian Inst. of Sci., Bangalore, India
Журнал:
Journal of Physics: Condensed Matter
Дата:
1992-08-24
Аннотация:
Mixed-valent systems based on Ce, Sm, Eu and Yb exhibit a wide range of behaviour with respect to valence changes under the application of pressure. The authors present a semi-phenomenological model for this behaviour based on competition effects between the usual elastic energy cost and the magnetic energy gain due to valence fluctuations. For the latter they use a mean-field Anderson lattice description and incorporate the effects of pressure by introducing a volume dependence to the Anderson model parameters in <sub>f</sub> and Delta . In contrast to existing models such as the Kondo Volume Collapse theory of Allen and Martin (1982), which describes magnetic to non-magnetic transitions without sizable valence change (e.g. gamma -Ce to alpha -Ce), the Anderson lattice model developed here describes systems with both small and large valence changes: the transition can be continuous (e.g. EuPd<sub>2</sub>Si<sub>2</sub>) or discontinuous (EuPd<sub>2</sub>Si<sub>2</sub> alloyed with Au).
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