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Автор G A Zlateva
Автор V N Popov
Автор M Gyulmezov
Автор L N Bozukov
Автор M N Iliev
Дата выпуска 1992-11-02
dc.description The polarized Raman spectra of Ca<sub>2</sub>CuO<sub>3</sub>, Ca<sub>1.8</sub>Sr<sub>0.2</sub>CuO<sub>3</sub> and Ca<sub>1.6</sub>Sr<sub>0.4</sub>CuO<sub>3</sub> single crystals and the IR transmission spectra of Ca<sub>2</sub>CuO<sub>3</sub> and Ca<sub>1.6</sub>Sr<sub>0.4</sub>CuO<sub>3</sub> have been measured. The frequencies of all Gamma -point phonons of Ca<sub>2</sub>CuO<sub>3</sub> have been determined on the basis of assignment of the one-phonon Raman (A<sub>g</sub>) and IR lines to definite normal modes and calculations of the lattice dynamics. The line assignment is consistent with earlier results for Ca<sub>1.8</sub>Sr<sub>0.2</sub>CuO<sub>3</sub> as well as with the line shifts upon substitution of Sr for Ca. The intensive broad lines in the (bb)-polarized Raman spectra of both Sr-free and Sr-substituted samples (in addition to the two A<sub>g</sub> lines already assigned) have been attributed to resonantly enhanced two-phonon scattering involving modes related to motions of Cu and/or O(2) atoms. A coincidence has been found between most of the line frequencies and half-widths in the (bb)-polarized Raman spectra and some of the maxima in the two-phonon density of states as obtained from lattice dynamics calculations.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Phonons in Ca<sub>2-x</sub>Sr<sub>x</sub>CuO<sub>3</sub> (x=0, 0.2 and 0.4): Raman and infrared spectroscopy, and lattice dynamics calculation
Тип paper
DOI 10.1088/0953-8984/4/44/015
Electronic ISSN 1361-648X
Print ISSN 0953-8984
Журнал Journal of Physics: Condensed Matter
Том 4
Первая страница 8543
Последняя страница 8550
Аффилиация G A Zlateva; Fac. of Phys., Sofia Univ., Bulgaria
Аффилиация V N Popov; Fac. of Phys., Sofia Univ., Bulgaria
Аффилиация M Gyulmezov; Fac. of Phys., Sofia Univ., Bulgaria
Аффилиация L N Bozukov; Fac. of Phys., Sofia Univ., Bulgaria
Аффилиация M N Iliev; Fac. of Phys., Sofia Univ., Bulgaria
Выпуск 44

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