| Автор | Y Y Yeung |
| Дата выпуска | 1992-11-30 |
| dc.description | The ionic positions of Gd<sup>3+</sup> at orthorhombic sites in CaF<sub>2</sub> with a nearby charge-compensating M<sup>+</sup> ion (M=Li, Na, K, Rb and Cs) are calculated from a reliable lattice relaxation model. The results are then employed in superposition model analyses of the corresponding spin parameters of the ground state 4f<sup>7</sup> <sup>8</sup>S<sub>7/2</sub> splitting of the Gd<sup>3+</sup> ion available in the literature. The superposition model analyses indicate that the spin parameters can best be described in terms of some intrinsic parameters which follow a parabolic dependence on the ligand distances in addition to the conventional power-law form, and hence also assert the cancelling nature of various physical mechanisms contributing to the ground state splitting of Gd<sup>3+</sup>. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | Local distortions and spin parameters of Gd<sup>3+</sup> in some orthorhombic CaF<sub>2</sub> complexes |
| Тип | paper |
| DOI | 10.1088/0953-8984/4/48/026 |
| Electronic ISSN | 1361-648X |
| Print ISSN | 0953-8984 |
| Журнал | Journal of Physics: Condensed Matter |
| Том | 4 |
| Первая страница | 9741 |
| Последняя страница | 9750 |
| Аффилиация | Y Y Yeung; Dept. of Appl. Phys., Hong Kong Polytech., Hong Kong |
| Выпуск | 48 |
