| Автор | A R Lim |
| Автор | S H Choh |
| Автор | M S Jang |
| Дата выпуска | 1992-02-10 |
| dc.description | Nuclear magnetic resonance spectra of <sup>209</sup>Bi(I=9/2) in the ferroelastic BiVO<sub>4</sub> single crystal has been investigated by employing a wide-line Varian spectrometer. Only three lines due to a large quadrupole interaction were measured at a fixed frequency of 6 MHz in the principal planes at room temperature. From the experimental data the quadrupole coupling constant E<sup>2</sup>qQ/h=79.2+or-0.1 MHz and asymmetry parameter eta =0.70+or-0.01 are determined; however, these values turn out to be quite different from the previous report obtained with a ceramic sample at liquid-nitrogen temperature. The principal axes of the electric field gradient tensor are determined for the first time, the x, y and z axes being the crystallographic c+25 degrees , a+25 degrees , and b axes, respectively. Thes directions are discussed in terms of the Bi-O bonds in the Bi-O polyhedra. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | Nuclear magnetic resonance of <sup>209</sup>Bi in a BiVO<sub>4</sub> single crystal |
| Тип | paper |
| DOI | 10.1088/0953-8984/4/6/026 |
| Electronic ISSN | 1361-648X |
| Print ISSN | 0953-8984 |
| Журнал | Journal of Physics: Condensed Matter |
| Том | 4 |
| Первая страница | 1607 |
| Последняя страница | 1613 |
| Аффилиация | A R Lim; Dept. of Phys., Korea Univ., Seoul, South Korea |
| Аффилиация | S H Choh; Dept. of Phys., Korea Univ., Seoul, South Korea |
| Аффилиация | M S Jang; Dept. of Phys., Korea Univ., Seoul, South Korea |
| Выпуск | 6 |
