Автор |
J Jansons |
Автор |
Z Rachko |
Автор |
J Valbis |
Автор |
J Andriessen |
Автор |
P Dorenbos |
Автор |
C W E van Eijk |
Автор |
N M Khaidukov |
Дата выпуска |
1993-03-08 |
dc.description |
The cross-luminescence (CRL) resulting from radiative electronic transitions from the mainly anion-related valence band to the uppermost cation core band has been studied in a number of complex halides containing CsCl, RbF, KF, and BaF<sub>2</sub>. The energy of the CRL photons is determined by the energy difference of the two bands, and the shapes of the spectra reflect the grouping of the molecular orbitals in the clusters involving cations with a hole in the core shell and nearest-neighbour halide ions. For crystals with more than one type of cation, the spectrum reveals information about the 'active' cation which contains the core hole and also about the other cations. Correlations have been established between the local symmetry of the clusters in different crystals and the number and position of the subbands in the CRL spectra. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Название |
Cross-luminescence of complex halide crystals |
Тип |
paper |
DOI |
10.1088/0953-8984/5/10/015 |
Electronic ISSN |
1361-648X |
Print ISSN |
0953-8984 |
Журнал |
Journal of Physics: Condensed Matter |
Том |
5 |
Первая страница |
1589 |
Последняя страница |
1596 |
Аффилиация |
J Jansons; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia |
Аффилиация |
Z Rachko; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia |
Аффилиация |
J Valbis; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia |
Аффилиация |
J Andriessen; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia |
Аффилиация |
P Dorenbos; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia |
Аффилиация |
C W E van Eijk; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia |
Аффилиация |
N M Khaidukov; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia |
Выпуск |
10 |