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Автор J Jansons
Автор Z Rachko
Автор J Valbis
Автор J Andriessen
Автор P Dorenbos
Автор C W E van Eijk
Автор N M Khaidukov
Дата выпуска 1993-03-08
dc.description The cross-luminescence (CRL) resulting from radiative electronic transitions from the mainly anion-related valence band to the uppermost cation core band has been studied in a number of complex halides containing CsCl, RbF, KF, and BaF<sub>2</sub>. The energy of the CRL photons is determined by the energy difference of the two bands, and the shapes of the spectra reflect the grouping of the molecular orbitals in the clusters involving cations with a hole in the core shell and nearest-neighbour halide ions. For crystals with more than one type of cation, the spectrum reveals information about the 'active' cation which contains the core hole and also about the other cations. Correlations have been established between the local symmetry of the clusters in different crystals and the number and position of the subbands in the CRL spectra.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Cross-luminescence of complex halide crystals
Тип paper
DOI 10.1088/0953-8984/5/10/015
Electronic ISSN 1361-648X
Print ISSN 0953-8984
Журнал Journal of Physics: Condensed Matter
Том 5
Первая страница 1589
Последняя страница 1596
Аффилиация J Jansons; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia
Аффилиация Z Rachko; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia
Аффилиация J Valbis; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia
Аффилиация J Andriessen; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia
Аффилиация P Dorenbos; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia
Аффилиация C W E van Eijk; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia
Аффилиация N M Khaidukov; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia
Выпуск 10

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