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Автор J J Bercier
Автор M Jirousek
Автор M Graetzel
Автор J J van der Klink
Дата выпуска 1993-11-01
dc.description The abrupt discontinuity of the background in the semi-infinite jellium results in a decaying oscillatory (Bardeen) spatial response of the electron gas. Related phenomena are the Friedel oscillations around an impurity in a metal, and the Ruderman-Kittel coupling between two localized magnetic moments embedded in a sea of conduction electrons. We have found that the <sup>109</sup>Ag (I= 1/2 ) NMR linewidth in nanometre-sized supported (and therefore isolated) silver particles shows a size effect that may be due to Bardeen-Friedel oscillations. The linewidth is also temperature dependent, in a way that cannot easily be explained as an effect of paramagnetic impurities; we suggest that thermal vibrations, known to have comparatively large amplitudes in small particles, wash out the abruptness in the background-charge discontinuity, and thus diminish the amplitude of the oscillations.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Evidence from NMR for temperature-dependent Bardeen-Friedel oscillations in nanometre-sized silver particles
Тип lett
DOI 10.1088/0953-8984/5/44/005
Electronic ISSN 1361-648X
Print ISSN 0953-8984
Журнал Journal of Physics: Condensed Matter
Том 5
Первая страница L571
Последняя страница L576
Аффилиация J J Bercier; Inst. de Phys. Exp., Ecole Polytech. Federale de Lausanne, Switzerland
Аффилиация M Jirousek; Inst. de Phys. Exp., Ecole Polytech. Federale de Lausanne, Switzerland
Аффилиация M Graetzel; Inst. de Phys. Exp., Ecole Polytech. Federale de Lausanne, Switzerland
Аффилиация J J van der Klink; Inst. de Phys. Exp., Ecole Polytech. Federale de Lausanne, Switzerland
Выпуск 44

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