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Автор Wen-cai Wang
Автор Yu Chen
Автор Tian-dou Hu
Дата выпуска 1994-03-14
dc.description The short-range order structures in some ternary ZrF<sub>4</sub>-BaF<sub>2</sub>-based glasses doped with EuF<sub>3</sub>, AlF<sub>3</sub> or NaF are studied by XAFS. The near-neighbour structures around Zr, Ba and Eu are determined and compared with that in binary ZrF<sub>4</sub>-BaF<sub>2</sub> glasses. The structural parameters of near neighbours around Zr and Ba are slightly reduced on addition of NaF or AlF<sub>3</sub>. Also, it is observed that the intensities of the 'white lines' in the L<sub>n</sub> and L<sub>m</sub> absorption edges of Eu and Ba in these glasses are different from those in corresponding fluorides. The causes leading to these changes are discussed. Meanwhile the differences between the bonding behaviour of Eu-F and that of Ba-F in the glasses are also discussed.
Формат application.pdf
Издатель Institute of Physics Publishing
Название The short-range order in some ternary ZrF<sub>4</sub>-based glasses
Тип paper
DOI 10.1088/0953-8984/6/11/005
Electronic ISSN 1361-648X
Print ISSN 0953-8984
Журнал Journal of Physics: Condensed Matter
Том 6
Первая страница 2159
Последняя страница 2168
Аффилиация Wen-cai Wang; Dept. of Phys., Beijing Univ., China
Аффилиация Yu Chen; Dept. of Phys., Beijing Univ., China
Аффилиация Tian-dou Hu; Dept. of Phys., Beijing Univ., China
Выпуск 11

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