| Автор | Tae Ho Yeom |
| Автор | Sung Ho Choh |
| Автор | Kyu Jeong Song |
| Автор | Min Su Jang |
| Дата выпуска | 1994-01-10 |
| dc.description | The domain structure of the ferroelastic BiVO<sub>4</sub> single crystal has been investigated using the nuclear magnetic resonance (NMR) of <sup>51</sup>V and by the electron paramagnetic resonance (EPR) of the Mn<sup>2+</sup> ions contained in the crystal as an impurity. The 14 resonance lines of <sup>51</sup>V (I=<sup>7</sup>/<sub>2</sub>) in a BiVO<sub>4</sub> crystal with the twin domain were measured in the crystallographic a-b (or c-b) and c-a (or a-c) planes with an FT NMR spectrometer. Two sets of Mn<sup>2</sup>+ EPR signals were also obtained in the c-a plane. These two sets of NMR and EPR signals originate from the twin-domain structure. From these two sets of experimental data from <sup>51</sup>V NMR and Mn<sup>2+</sup> EPR, it is confirmed that the BiVO<sub>4</sub> single crystal has the prominent (W-plane) domain wall reported previously. The investigated domain structure is found to be stable with time in contrast with a previous report by Baran et al. The previous model of the twinning mechanism derived from NMR and X-ray diffraction data has been improved by employing the EPR results. The observed W plane of the domain wall in BiVO<sub>4</sub> can be explained by the ferroelastic species 4/mmm F 2/m instead of 4/m F 2/m. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | The domain structure of ferroelastic BiVO<sub>4</sub> studied by magnetic resonances |
| Тип | paper |
| DOI | 10.1088/0953-8984/6/2/010 |
| Electronic ISSN | 1361-648X |
| Print ISSN | 0953-8984 |
| Журнал | Journal of Physics: Condensed Matter |
| Том | 6 |
| Первая страница | 383 |
| Последняя страница | 392 |
| Аффилиация | Tae Ho Yeom; Dept. of Phys., Korea Univ., Seoul, South Korea |
| Аффилиация | Sung Ho Choh; Dept. of Phys., Korea Univ., Seoul, South Korea |
| Аффилиация | Kyu Jeong Song; Dept. of Phys., Korea Univ., Seoul, South Korea |
| Аффилиация | Min Su Jang; Dept. of Phys., Korea Univ., Seoul, South Korea |
| Выпуск | 2 |
