A new phase transition in the T-P diagram of C<sub>60</sub> fullerite
I O Bashkin; V I Rashchupkin; A F Gurov; A P Moravsky; O G Rybchenkot; N P Kobelev; Ya M Soifer; E G Ponyatovsky; I O Bashkin; Inst. of Solid State Phys., Acad. of Sci., Chernogolovka, Russia; V I Rashchupkin; Inst. of Solid State Phys., Acad. of Sci., Chernogolovka, Russia; A F Gurov; Inst. of Solid State Phys., Acad. of Sci., Chernogolovka, Russia; A P Moravsky; Inst. of Solid State Phys., Acad. of Sci., Chernogolovka, Russia; O G Rybchenkot; Inst. of Solid State Phys., Acad. of Sci., Chernogolovka, Russia; N P Kobelev; Inst. of Solid State Phys., Acad. of Sci., Chernogolovka, Russia; Ya M Soifer; Inst. of Solid State Phys., Acad. of Sci., Chernogolovka, Russia; E G Ponyatovsky; Inst. of Solid State Phys., Acad. of Sci., Chernogolovka, Russia
Журнал:
Journal of Physics: Condensed Matter
Дата:
1994-09-05
Аннотация:
The earlier high-pressure study of C<sub>60</sub> concentrated on the orientational transition and room-temperature transformations observed in diamond anvils. This work presents a part of the T-P phase diagram for solid C<sub>60</sub> at pressures up to 20 kbar in the temperature range extended to 700 K. A new phase region is outlined herein. The new phase is retained to ambient conditions and preliminarily characterized. The new phase is more dense than the initial C<sub>60</sub> by at least 8.5% and less compressible by approximately 1.5 times. Its crystal structure is very different from the well known face-centred cubic and simple cubic phases, and its recovery to a cubic phase is associated with an endothermal heat effect of approximately 23 J g<sup>-1</sup>. The nature and the thermodynamic stability of the new phase are discussed in connection with polymerization of C<sub>60</sub> molecules, which seems likely.
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