Автор |
Youn-Doo Kim |
Автор |
Jun-Gill Kang |
Дата выпуска |
1994-10-17 |
dc.description |
The emission from KCl:Bi<sup>3+</sup> excited in the X absorption band (i.e. between the A and B absorption bands) was measured as a function of temperature. The polarized emission spectrum and the angular dependence of polarization ratio were also investigated. The X-band excitation produces two emission bands peaking at 345 and 395 nm, the centres of which are not the same. The loosely bonded Cl<sup>-</sup> ion arising from the substitution of Bi<sup>3+</sup> ions into the KCl lattice is assumed to be the colour centre for the X-band emission. The definitive assignment of the two emission bands is presented in terms of the relaxed excited states of the perturbed Cl<sup>-</sup> ion, in which the Jahn-Teller interaction coupling to the B<sub>1</sub> and B<sub>2</sub> vibronic modes is taken into account. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Название |
Luminescence of KCl:Bi<sup>3+</sup> excited at the X absorption band |
Тип |
paper |
DOI |
10.1088/0953-8984/6/42/024 |
Electronic ISSN |
1361-648X |
Print ISSN |
0953-8984 |
Журнал |
Journal of Physics: Condensed Matter |
Том |
6 |
Первая страница |
8949 |
Последняя страница |
8958 |
Аффилиация |
Youn-Doo Kim; Dept. of Chem., Chungnam Nat. Univ., Daejon, South Korea |
Аффилиация |
Jun-Gill Kang; Dept. of Chem., Chungnam Nat. Univ., Daejon, South Korea |
Выпуск |
42 |