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Автор Youn-Doo Kim
Автор Jun-Gill Kang
Дата выпуска 1994-10-17
dc.description The emission from KCl:Bi<sup>3+</sup> excited in the X absorption band (i.e. between the A and B absorption bands) was measured as a function of temperature. The polarized emission spectrum and the angular dependence of polarization ratio were also investigated. The X-band excitation produces two emission bands peaking at 345 and 395 nm, the centres of which are not the same. The loosely bonded Cl<sup>-</sup> ion arising from the substitution of Bi<sup>3+</sup> ions into the KCl lattice is assumed to be the colour centre for the X-band emission. The definitive assignment of the two emission bands is presented in terms of the relaxed excited states of the perturbed Cl<sup>-</sup> ion, in which the Jahn-Teller interaction coupling to the B<sub>1</sub> and B<sub>2</sub> vibronic modes is taken into account.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Luminescence of KCl:Bi<sup>3+</sup> excited at the X absorption band
Тип paper
DOI 10.1088/0953-8984/6/42/024
Electronic ISSN 1361-648X
Print ISSN 0953-8984
Журнал Journal of Physics: Condensed Matter
Том 6
Первая страница 8949
Последняя страница 8958
Аффилиация Youn-Doo Kim; Dept. of Chem., Chungnam Nat. Univ., Daejon, South Korea
Аффилиация Jun-Gill Kang; Dept. of Chem., Chungnam Nat. Univ., Daejon, South Korea
Выпуск 42

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