Impurities in nominally pure KTaO<sub>3</sub>: evidence from electron spin resonance
M D Glinchuk; V V Laguta; I P Bykov; J Rosa; L Jastrabik; M D Glinchuk; Inst. of Problems in Mater. Sci., Acad. of Sci., Kiev, Ukraine; V V Laguta; Inst. of Problems in Mater. Sci., Acad. of Sci., Kiev, Ukraine; I P Bykov; Inst. of Problems in Mater. Sci., Acad. of Sci., Kiev, Ukraine; J Rosa; Inst. of Problems in Mater. Sci., Acad. of Sci., Kiev, Ukraine; L Jastrabik; Inst. of Problems in Mater. Sci., Acad. of Sci., Kiev, Ukraine
Журнал:
Journal of Physics: Condensed Matter
Дата:
1995-03-27
Аннотация:
The ESR investigation of nominally pure KTaO<sub>3</sub> was carried out at 4.2 K<T<77 K. Two ESR spectra were observed for the first time. The first spectrum with cubic symmetry was shown to be that of Gd<sup>3+</sup> substituted for K<sup>+</sup>. The analysis of the spectrum line intensities and widths gave no evidence about the quasi-static displacements of tantalum ions in the lattice assumed earlier. The second spectrum had axial symmetry and its source was identified as a new off-centre impurity ion Fe<sup>+</sup> substituted for K<sup>+</sup> in KTaO<sub>3</sub>. The surrounding oxygen ion displacements were shown to be the main reason for the Fe<sup>+</sup> ESR spectra axiality. The estimation of these displacements Delta x was carried out in the framework of crystalline-field theory and appeared to be about 0.2 AA.
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