| Автор | U Stuhr |
| Автор | H Wipf |
| Автор | T J Udovic |
| Автор | J Weissmuller |
| Автор | H Gleiter |
| Дата выпуска | 1995-01-09 |
| dc.description | The vibrational excitations and the position of hydrogen in nanocrystalline palladium were investigated by means of inelastic neutron-scattering and H solubility measurements. The study focuses on the H concentration regime (<or=4.8 at.% H) where, at room temperature, no precipitation of the H in a hydride phase ( beta -phase) was observed. In this concentration regime, the solubility measurements show an enhanced H solubility relative to coarse-grained Pd. The neutron-scattering experiments show that this additional H is incorporated in the grain boundaries and at the surface of the grains. Surface modes of H at approximately 90 and 120 meV were identified. Compared to coarse-grained Pd, no change in the H solubility was found for the crystal lattice of the nanosized grains. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | The vibrational excitations and the position of hydrogen in nanocrystalline palladium |
| Тип | paper |
| DOI | 10.1088/0953-8984/7/2/002 |
| Electronic ISSN | 1361-648X |
| Print ISSN | 0953-8984 |
| Журнал | Journal of Physics: Condensed Matter |
| Том | 7 |
| Первая страница | 219 |
| Последняя страница | 230 |
| Аффилиация | U Stuhr; Inst. fur Festkorperphys., Tech. Hochschule Darmstadt, Germany |
| Аффилиация | H Wipf; Inst. fur Festkorperphys., Tech. Hochschule Darmstadt, Germany |
| Аффилиация | T J Udovic; Inst. fur Festkorperphys., Tech. Hochschule Darmstadt, Germany |
| Аффилиация | J Weissmuller; Inst. fur Festkorperphys., Tech. Hochschule Darmstadt, Germany |
| Аффилиация | H Gleiter; Inst. fur Festkorperphys., Tech. Hochschule Darmstadt, Germany |
| Выпуск | 2 |
