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Автор A Hedoux
Автор Y Guinet
Автор F X Leduc
Автор M More
Автор M Foulon
Автор F Danede
Автор G Odou
Дата выпуска 1995-09-25
dc.description Differential scanning calorimetry and x-ray diffraction experiments performed in K<sub>2</sub>ZnCl<sub>4</sub> have clearly revealed that two phenomena are involved in the phase transition process at 148 K. The first one corresponds to a slow reorganization of the tetrahedron configuration responsible for the development of a diffuse scattering localized on (a*+b*)/2 points of the reciprocal space. The second phenomenon corresponds to the growth of the (a*+b*)/2 superstructure phase. A very new feature results from observation of a competitive character between these two phenomena. It is shown that the kinetic behaviour of the first phenomenon and its possible correlation to the crystal growth defects are certainly involved in the phase transition process at 148 K.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Evidence of two competitive phenomena involved in the phase transition process at 144 K in K<sub>2</sub>ZnCl<sub>4</sub> from x-ray diffraction and DSC experiments
Тип paper
DOI 10.1088/0953-8984/7/39/007
Electronic ISSN 1361-648X
Print ISSN 0953-8984
Журнал Journal of Physics: Condensed Matter
Том 7
Первая страница 7651
Последняя страница 7662
Аффилиация A Hedoux; Lab. de Dynamique et Structure des Mater. Moleculaires, Lille I Univ., Villeneuve d'Ascq, France
Аффилиация Y Guinet; Lab. de Dynamique et Structure des Mater. Moleculaires, Lille I Univ., Villeneuve d'Ascq, France
Аффилиация F X Leduc; Lab. de Dynamique et Structure des Mater. Moleculaires, Lille I Univ., Villeneuve d'Ascq, France
Аффилиация M More; Lab. de Dynamique et Structure des Mater. Moleculaires, Lille I Univ., Villeneuve d'Ascq, France
Аффилиация M Foulon; Lab. de Dynamique et Structure des Mater. Moleculaires, Lille I Univ., Villeneuve d'Ascq, France
Аффилиация F Danede; Lab. de Dynamique et Structure des Mater. Moleculaires, Lille I Univ., Villeneuve d'Ascq, France
Аффилиация G Odou; Lab. de Dynamique et Structure des Mater. Moleculaires, Lille I Univ., Villeneuve d'Ascq, France
Выпуск 39

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