Автор |
L G Grigorjeva |
Автор |
E A Kotomin |
Автор |
D K Millers |
Автор |
R I Eglitis |
Дата выпуска |
1995-02-13 |
dc.description |
The decay kinetics of the excitonic luminescence observed at 2.5 eV in AgCl after pulsed laser irradiation was measured in wide temperature (10-200 K), time (20 ns-10<sup>-2</sup> s) and luminescence intensity intervals. It is shown that, at low temperatures, the decay of luminescence is due to the static tunnelling recombination of unidentified shallow electron centres (with a wavefunction radius of about 30 AA) with immobile self-trapped holes. At temperatures above 80 K the relevant luminescence decay starts to differ from that at 10 K and does not obey the usual exponential or second-order kinetics; it was interpreted as diffusion-controlled annihilation within close (geminate) Frenkel pairs of radiation defects. These latter are assumed to be Ag<sup>2+</sup>V<sub>c</sub><sup>-</sup> and interstitial silver atoms Ag<sub>i</sub><sup>0</sup>, respectively. Silver atoms are characterized by the 0.15 eV activation energies of hops and a small wavefunction radius of about 1 AA. Thermal quenching of this luminescence is discussed; its activation energy (0.33 eV) corresponds to cation vacancy migration. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Название |
The decay kinetics of excitonic luminescence in AgCl crystals |
Тип |
paper |
DOI |
10.1088/0953-8984/7/7/027 |
Electronic ISSN |
1361-648X |
Print ISSN |
0953-8984 |
Журнал |
Journal of Physics: Condensed Matter |
Том |
7 |
Первая страница |
1483 |
Последняя страница |
1491 |
Аффилиация |
L G Grigorjeva; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia |
Аффилиация |
E A Kotomin; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia |
Аффилиация |
D K Millers; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia |
Аффилиация |
R I Eglitis; Inst. of Solid State Phys., Latvia Univ., Riga, Latvia |
Выпуск |
7 |