| Автор | A Leithe-Jasper |
| Автор | R Skomski |
| Автор | Qinian Qi |
| Автор | J M D Coey |
| Автор | F Weitzer |
| Автор | P Rogl |
| Дата выпуска | 1996-05-06 |
| dc.description | The tetragonal ternary intermetallics , Au, Si, Ge, Sn, Pb), which all crystallize in the structure, are found to absorb approximately 12 - 18 hydrogen atoms/formula unit in a largely irreversible reaction at 390 K under a gas pressure of 1 bar. The unit cell volume expands by 10 - 15% without any change in the crystal symmetry and structure type, corresponding to an increase of volume per hydrogen atom of . Lattice expansion is highly anisotropic, being an order of magnitude greater along c than along a. The anisotropic lattice expansion and hydrogenation characteristics are explained in a model where the hydrogen atoms enter the nm rare-earth slabs in an amount controlled by the element X. The nm iron slabs expand little. Magnetization and Mössbauer measurements on the parent compounds show them to be essentially antiferromagnetic with a net moment of formula unit but on hydrogenation there is ferromagnetic behaviour with a moment of formula unit at room temperature. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | Hydrogen in intermetallic compounds (RE = Pr, Nd; X=Ag, Au, Si, Ge, Sn, Pb) |
| Тип | paper |
| DOI | 10.1088/0953-8984/8/19/020 |
| Electronic ISSN | 1361-648X |
| Print ISSN | 0953-8984 |
| Журнал | Journal of Physics: Condensed Matter |
| Том | 8 |
| Первая страница | 3453 |
| Последняя страница | 3469 |
| Выпуск | 19 |
