Автор |
S Ohno |
Автор |
A C Barnes |
Автор |
J E Enderby |
Дата выпуска |
1996-05-20 |
dc.description |
The electrical conductivity , thermopower S and magnetic susceptibility of liquid have been measured as a function of c. It is found that decreases monotonically on addition of AgCl to S and reaches a value typical of a molten salt when at which point a semiconductor to molten salt transition takes place. The thermopower is negative for c > 0.3 at which composition it changes sign. The magnetic susceptibility measurements show a steady increase with c, consistent with the changes in the ionic diamagnetism and a significant Pauli contribution from the electrons for the S rich compositions. The behaviour of the system is analysed and described in terms of a simple ionic band picture using a Kubo - Greenwood formalism in which the conductivity gap increases with increasing concentration of AgCl. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Название |
The electrical and magnetic properties of molten mixtures |
Тип |
paper |
DOI |
10.1088/0953-8984/8/21/006 |
Electronic ISSN |
1361-648X |
Print ISSN |
0953-8984 |
Журнал |
Journal of Physics: Condensed Matter |
Том |
8 |
Первая страница |
3785 |
Последняя страница |
3794 |
Выпуск |
21 |