From the density-functional theory to `density-free' approximation schemes; a one-particle-ensemble formalism
Behnam Farid; Behnam Farid; Cavendish Laboratory, Department of Physics, University of Cambridge, Madingley Road, Cambridge CB3 0HE, UK
Журнал:
Journal of Physics: Condensed Matter
Дата:
1996-08-26
Аннотация:
On the basis of some principles of the theory of density functionals, we obtain a fully specified ensemble of eigenstates of an effective (one-body) Hamiltonian whose average energy is identical to the ground-state total energy of the interacting system. It is shown that within the present framework accurate approximation schemes can be devised through which the ground-state total energy is obtained by the knowledge of two quantities only, the average density of the electrons, and the external potential.
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