| Автор | Jan Skov Pedersen |
| Автор | Andy Horsewell |
| Автор | Morten Eldrup |
| Дата выпуска | 1996-10-28 |
| dc.description | The annealing behaviour of bulk copper containing 2.6 at.% krypton has been studied by small-angle neutron scattering (SANS) and transmission electron microscopy (TEM). In addition positron annihilation spectroscopy (PAS) and mass-density measurements (MDM) were made. In the as-prepared and annealed material a high density of krypton precipitates (`bubbles') exists. Special emphasis is put on different approaches to the analysis of the SANS data. Differences between the results from the various analyses are pointed out and discussed. Polydisperse models clearly give the most extensive information, i.e. the size distribution of the Kr bubbles and integral parameters derived from it (i.e. bubble volume, total surface area and average radius). It is demonstrated that a correct choice of form factor is important for the reliability of the derived size distribution. In TEM a high degree of overlap of bubble images is observed and corrected for. Good agreement between the shapes of SANS and TEM size distributions is found, while differences in amplitude are ascribed to experimental uncertainties. Average krypton densities in the bubbles as well as fractional cavity volumes derived from PAS and MDM are found to be in good agreement, but the cavity volumes are clearly larger than the total bubble volumes obtained from the SANS and TEM size distributions. Above roughly bubble growth takes place. Two different mechanisms for the initiation of growth are discussed. At the higher annealing temperatures the growth in bubble size and total volume fraction is explained by bubble migration and coalescence followed by absorption of thermal vacancies. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | A small-angle neutron scattering and transmission electron microscopy study of krypton precipitates in copper |
| Тип | paper |
| DOI | 10.1088/0953-8984/8/44/001 |
| Electronic ISSN | 1361-648X |
| Print ISSN | 0953-8984 |
| Журнал | Journal of Physics: Condensed Matter |
| Том | 8 |
| Первая страница | 8431 |
| Последняя страница | 8455 |
| Выпуск | 44 |
