Free energy of electric double layers around finite particles
Emmanuel Trizac; Jean-Pierre Hansen; Emmanuel Trizac; Laboratoire de Physique (URA 1325 du CNRS), Ecole Normale Supérieure de Lyon, 69364 Lyon Cédex 07, France; Jean-Pierre Hansen; Laboratoire de Physique (URA 1325 du CNRS), Ecole Normale Supérieure de Lyon, 69364 Lyon Cédex 07, France
Журнал:
Journal of Physics: Condensed Matter
Дата:
1996-11-18
Аннотация:
The classic problem of evaluating the free energy of an electric double layer around a planar electrode or polyion through an appropriate charging process is reconsidered, within the Poisson - Boltzmann framework. After a brief consideration of an infinite planar electrode, we examine finite-size effects. An application is made to swollen arrays of disc-shaped clay platelets.
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