Dynamic structure factor scaling in dense gelling silica suspensions
B D Butler; C D Muzny; H J M Hanley; B D Butler; Physical and Chemical Properties Division, National Institute of Standards and Technology, Boulder, CO 80303, USA; C D Muzny; Physical and Chemical Properties Division, National Institute of Standards and Technology, Boulder, CO 80303, USA; H J M Hanley; Physical and Chemical Properties Division, National Institute of Standards and Technology, Boulder, CO 80303, USA
Журнал:
Journal of Physics: Condensed Matter
Дата:
1996-11-18
Аннотация:
Small-angle neutron scattering data from dense (30% by mass) gelling 7 nm colloidal silica spheres are presented. The coarsening process that occurs during gelation exhibits temporal self-similarity, and the time-dependent structure factor obeys the dynamic scaling relation . Here, q is the scattered wavevector, is the location of the low-angle peak in is a time-independent characteristic structure function which has a maximum at x = 1, and is the fractal dimension. Connections between the silica gelation and spinodal decomposition in a simple fluid are reviewed.
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