Raman spectra of DRADP-25 dipolar glass: evidence for the mixed ferroelectric - glass phase
Yu I Yuzyuk; I Gregora; V Vorlícek; J Petzelt; Yu I Yuzyuk; Institute of Physics, Academy of Sciences of the Czech Republic, Na Slovance 2, 180 40 Prague 8, Czech Republic; I Gregora; Institute of Physics, Academy of Sciences of the Czech Republic, Na Slovance 2, 180 40 Prague 8, Czech Republic; V Vorlícek; Institute of Physics, Academy of Sciences of the Czech Republic, Na Slovance 2, 180 40 Prague 8, Czech Republic; J Petzelt; Institute of Physics, Academy of Sciences of the Czech Republic, Na Slovance 2, 180 40 Prague 8, Czech Republic
Журнал:
Journal of Physics: Condensed Matter
Дата:
1996-01-29
Аннотация:
Raman spectra of a (DRADP-25) mixed crystal have been investigated in the 8 - 300 K temperature range for all fundamental polarization geometries. As in the case of DRADP-50, the spectra can be interpreted in terms of vibrational modes of principal structural units. Analysis of the temperature dependence of peak positions and halfwidths has shown two characteristic temperature regions (200 - 220 K and 110 - 120 K) where incipient cluster formation and freezing of individual structural units takes place in this compound on cooling through the dipolar glass transition. In contrast to those for DRADP-50, the Raman spectra of DRADP-25 reveal additionally the onset of incipient ferroelectric clustering and the existence of a low-temperature mixed ferroelectric - glass phase.
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