A neutron diffraction study of the superionic transition in with x = 0.06
M Hofmann; S Hull; G J McIntyre; C C Wilson
Журнал:
Journal of Physics: Condensed Matter
Дата:
1997-01-27
Аннотация:
We have investigated the high-temperature superionic transition of the anion-excess fluorite with x = 0.06 using both monochromatic and time-of-flight Laue single-crystal neutron diffraction. The measured Bragg intensities indicate that the cuboctahedral defect clusters found at ambient temperature start to break up into smaller fragments even below the superionic transition temperature, . Information concerning the local defect configuration at T = 1173 K has been provided by modelling the measured distribution of the coherent elastic diffuse scattering within the plane of reciprocal space. The high-temperature defects are of the `Willis' type and strongly resemble the short-lived Frenkel clusters found in the pure fluorites such as above .
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