Автор |
D Brown |
Автор |
M D Crapper |
Автор |
K H Bedwell |
Автор |
M T Butterfield |
Автор |
S J Guilfoyle |
Автор |
A E R Malins |
Автор |
M Petty |
Дата выпуска |
1997-10-27 |
dc.description |
The valence band electronic structure of the intermetallic compounds and has been investigated by means of synchrotron radiation ultraviolet photoemission. The spectra exhibit band structure extending to approximately 8 eV below the Fermi level for each alloy. Utilizing the Cooper minimum in the Pt 5d photoionization cross-section, the partial densities of states have been empirically determined. The results indicate that the d bands of the constituent metals completely overlap. The V 3d states contribute most strongly to the valence band immediately below the Fermi level. In contrast, the highest occupied density of states for the Mn 3d band lies approximately 2.6 eV below the Fermi level. For , 3p to 3d resonant photoemission confirms the results obtained at the Pt 5d Cooper minimum. However, no clear evidence for a corresponding V 3p to 3d resonance was observed in . This may indicate that the V d states in are significantly less localized than the Mn d states in . The empirical results for each alloy have been compared with theoretical calculations from the literature and provide good agreement in each case. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Название |
Experimental determination of the partial density of states for the binary alloys and |
Тип |
paper |
DOI |
10.1088/0953-8984/9/43/026 |
Electronic ISSN |
1361-648X |
Print ISSN |
0953-8984 |
Журнал |
Journal of Physics: Condensed Matter |
Том |
9 |
Первая страница |
9435 |
Последняя страница |
9443 |
Аффилиация |
D Brown; Physics Department, Loughborough University, Loughborough LE11 3TU, UK |
Аффилиация |
M D Crapper; Physics Department, Loughborough University, Loughborough LE11 3TU, UK |
Аффилиация |
K H Bedwell; Physics Department, Loughborough University, Loughborough LE11 3TU, UK |
Аффилиация |
M T Butterfield; Physics Department, Loughborough University, Loughborough LE11 3TU, UK |
Аффилиация |
S J Guilfoyle; Physics Department, Loughborough University, Loughborough LE11 3TU, UK |
Аффилиация |
A E R Malins; Physics Department, Loughborough University, Loughborough LE11 3TU, UK |
Аффилиация |
M Petty; Physics Department, Loughborough University, Loughborough LE11 3TU, UK |
Выпуск |
43 |