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Автор D Fuhrmann
Автор Ch Wöll
Дата выпуска 1998-12-17
dc.description The nature of the mechanism governing the damping of molecular motion relative to a solid substrate has been investigated by a systematic study of molecular frustrated translations. Using scattering of thermal energy He-atoms, these vibrations located in the far-infrared regime (<15 meV) have been determined for prototype lubricant molecules, octane and other saturated hydrocarbons, adsorbed on a variety of different substrates, namely hydrogen-terminated diamond C(111), Pb(111), clean and hydrogen passivated Ru(0001) as well as on Cu(111). In most cases the lifetime of the frustrated translational modes is in good agreement with that computed from theoretical models considering only phononic damping. Exceptions to this rule (Pb(111) and Ru(0001)) are discussed. The results suggest that generally electronic contributions to sliding friction are weak; only in cases with significant electronic coupling between molecule and substrate does electronic friction dominate phononic friction.
Формат application.pdf
Издатель Institute of Physics Publishing
Название The microscopic origins of sliding friction: a spectroscopic approach
Тип paper
DOI 10.1088/1367-2630/1/1/001
Electronic ISSN 1367-2630
Журнал New Journal of Physics
Том 1
Первая страница 1
Последняя страница 1
Аффилиация D Fuhrmann; Physikalische Chemie I, Ruhr Universität Bochum, 44780 Bochum, Germany; Max-Planck-Institut für Strömungsforschung, Bunsenstr. 10, 37073 Göttingen, Germany
Аффилиация Ch Wöll; Physikalische Chemie I, Ruhr Universität Bochum, 44780 Bochum, Germany; Max-Planck-Institut für Strömungsforschung, Bunsenstr. 10, 37073 Göttingen, Germany
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