Damping of Rotations of Quadrupolar Molecules at Metal Surfaces due to Excitation of Electron-Hole Pairs
Charlotta M Hedenäs; Charlotta M Hedenäs; Institute of Theoretical Physics, Chalmers University of Technology, S-412 96 Göteborg, Sweden
Журнал:
Physica Scripta
Дата:
1986-11-01
Аннотация:
The damping of rotations of a hydrogen molecule - modelled by a point quadrupole - due to the excitation of electron-hole pairs in a nearby Cu surface - modelled by a semi-infinite jellium - is calculated. The lifetimes of the rotational states depend on the distance d between the molecule and the surface asymptotically as d<sup>6</sup>. For H<sub>2</sub> physisorbed on Cu the lifetimes are found to be of the order of 10<sup>-9</sup> s, a value 2-3 orders of magnitude too large to explain widths measured by vibrational spectroscopy.
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