The self-organized phase of bulk P <sub>x</sub> Se <sub>1 − x</sub> glasses
D. G. Georgiev; P. Boolchand; H. Eckert; M. Micoulaut; K. Jackson
Журнал:
EPL (Europhysics Letters)
Дата:
2003-04-01
Аннотация:
Modulated Scanning Calorimetry shows the non-reversing heat flow near T<sub>g</sub> to display a sharply defined global minimum in the 0.28 < x < 0.40 range, identified with the self-organized phase (SOP) of titled glasses. <sup>31</sup>P NMR, Raman scattering and constraint counting algorithms suggest this phase to consist of two distinct global morphologies; a Se-rich backbone that has a dimensionality 2 < d < 3, and P-rich ribbons that have d ≃ 1. The ribbons dominate the physical behavior of stressed rigid (0.40 < x < 0.50) glasses with unusual consequences.
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