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Автор R. R. Netz
Дата выпуска 2003-08-01
dc.description Using Brownian-Dynamics simulations, a two-dimensional mixture of charged soft spheres is considered as a model system for cat-anionic lipid layers in tangential electric fields. Electrophoretic mobilities and diffusion constants are determined for a wide range of densities, electric field and Coulomb coupling strengths; the experimentally discovered violation of the Nernst-Einstein relation is reproduced for elevated densities. At large driving fields, a non-equilibrium transition into a charge-modulated structure (at finite Coulomb interaction between particles) or a macroscopic phase separation (at vanishing Coulomb coupling) is found, which might be experimentally reached with mixtures of rather incompatible cationic and anionic lipids.
Формат application.pdf
Издатель Institute of Physics Publishing
Копирайт 2003 EDP Sciences
Название Conduction and diffusion in two-dimensional electrolytes
Тип lett
DOI 10.1209/epl/i2003-00557-x
Electronic ISSN 1286-4854
Print ISSN 0295-5075
Журнал EPL (Europhysics Letters)
Том 63
Первая страница 616
Последняя страница 622
Аффилиация R. R. Netz; Sektion Physik, LMU - Theresienstr. 37, 80333 München, Germany
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