Interactions between polyelectrolyte-macroion complexes
H. Boroudjerdi; R. R. Netz; H. Boroudjerdi; Sektion Physik, LMU - Theresienstr. 37, 80333 München, Germany; R. R. Netz; Sektion Physik, LMU - Theresienstr. 37, 80333 München, Germany
Журнал:
EPL (Europhysics Letters)
Дата:
2003-11-01
Аннотация:
We consider structures formed by one semiflexible polyelectrolyte (PE) and one oppositely charged sphere and calculate the interaction between two such complexes within the ground-state approximation, where the PE assumes its optimal configuration. Using parameters appropriate for DNA-histone systems, we find the second virial coefficient of inter-complex interactions to be negative for intermediate salt concentrations within the range where stable complexes are formed, in agreement with experiments. A simple screened monopole-dipole model reproduces these findings.
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