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Автор Allahverdyan, A. E.
Автор Gevorkian, S. G.
Автор Simonian, A.
Дата выпуска 2009-06-01
dc.description Based on the Zimm-Bragg model we study cooperative helix-coil transition driven by a finite-speed change of temperature. There is an asymmetry between the coil → helix and helix → coil transition: the latter is displayed already for finite speeds, and takes shorter time than the former. This hysteresis effect has been observed experimentally, and it is explained here via quantifying system's stability in the vicinity of the critical temperature. A finite-speed cooling induces a non-equilibrium helical phase with the correlation length larger than in equilibrium. In this phase the characteristic length of the coiled domain and the non-equilibrium specific heat can display an anomalous response to temperature changes. Several pertinent experimental results on the kinetics of helical biopolymers are discussed in detail.
Формат application.pdf
Издатель Institute of Physics Publishing
Копирайт Europhysics Letters Association
Название Kinetics of the helix-coil transition
Тип lett
DOI 10.1209/0295-5075/86/53002
Electronic ISSN 1286-4854
Print ISSN 0295-5075
Журнал EPL (Europhysics Letters)
Том 86
Первая страница 53002
Последняя страница 53007
Аффилиация Allahverdyan, A. E.; Yerevan Physics Institute - Alikhanian Brothers Street 2, Yerevan 375036, Armenia
Аффилиация Gevorkian, S. G.; Yerevan Physics Institute - Alikhanian Brothers Street 2, Yerevan 375036, Armenia
Аффилиация Simonian, A.; Materials Research and Education Center - 275 Wilmore Auburn University, Auburn AL 36849-5341, USA
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