Electron collisions with the hydrides PH<sub>3</sub>, AsH<sub>3</sub> and SbH<sub>3</sub>
M H F Bettega; M A P Lima
Журнал:
Journal of Physics B: Atomic, Molecular and Optical Physics
Дата:
2004-10-14
Аннотация:
We report integral cross sections for the elastic scattering of low-energy electrons by the hydrides PH<sub>3</sub>, AsH<sub>3</sub> and SbH<sub>3</sub>. To calculate the cross sections, we employed the Schwinger multichannel method with pseudopotentials (Bettega et al 1993 Phys. Rev. A 47 1111) at the static-exchange plus polarization level of approximation for incident energies from 0.5 to 8 eV. For PH<sub>3</sub>, we compare our integral cross section with the recent total cross section measured by Szmytkowski et al (2004 J. Phys. B: At. Mol. Opt. Phys. 37 1833) and find good agreement in shape. In particular, our calculated elastic integral cross section for PH<sub>3</sub> also shows the two structures reported by the experiment. We have found that the three hydrides present a Ramsauer–Townsend minimum at around 1 eV.
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