| Автор | Emi Shinohara |
| Автор | Miho Yamauchi |
| Автор | Shin’ichi Ishimaru |
| Автор | Ryuichi Ikeda |
| Дата выпуска | 2003-11-05 |
| dc.description | Structures and dynamics of n-dodecyltrimethylammonium ions intercalated into sodium octosilicate and tetrasilicicfluoromica were studied by powder x-ray diffraction, and <sup>13</sup>C CP/MAS and <sup>1</sup>H NMR measurements. In the octosilicate, cations form a 2D-crystalline state in which long axes of intercalated alkylammonium ions were shown to be inclined to silicate layers and polymethylene chains (–CH<sub>2</sub>–)<sub>n</sub> take the all-trans conformation. On the other hand, in the tetrasilicicfluoromica, cations form disordered arrangements with random conformations of alkyl-chains, considered to be in a 2D-amorphous state. Based on the NMR results, the dynamic behaviour of these ions in 2D space is discussed. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Копирайт | IOP Publishing Ltd |
| Название | Structures and dynamics of n-dodecyltrimethylammonium ions intercalated into sodium octosilicate and tetrasilicicfluoromica |
| Тип | paper |
| DOI | 10.1088/0953-8984/15/43/009 |
| Electronic ISSN | 1361-648X |
| Print ISSN | 0953-8984 |
| Журнал | Journal of Physics: Condensed Matter |
| Том | 15 |
| Первая страница | 7253 |
| Последняя страница | 7259 |
| Аффилиация | Emi Shinohara; Department of Chemistry, University of Tsukuba, 305-8571 Tsukuba, Japan |
| Аффилиация | Miho Yamauchi; Department of Chemistry, University of Tsukuba, 305-8571 Tsukuba, Japan |
| Аффилиация | Shin’ichi Ishimaru; Department of Chemistry, University of Tsukuba, 305-8571 Tsukuba, Japan |
| Аффилиация | Ryuichi Ikeda; Department of Chemistry, University of Tsukuba, 305-8571 Tsukuba, Japan |
| Выпуск | 43 |
