| Автор | Anthonysamy, Arockiam |
| Автор | Balasubramanian, Sengottuvelan |
| Автор | Muthuraaman, Bhagavathiachari |
| Автор | Maruthamuthu, Pichai |
| Дата выпуска | 2007-03-07 |
| dc.description | The synthesis of an Ru(II) complex derived from 4′-(4-methacryloyloxymethylphenyl)- 2,2′:6′,2′′ terpyridine ligand, together with its spectral and electrochemical properties, has been described. The application of this complex, which does not possess the usual anchoring groups like carboxylate or phosphate, in a dye sensitized nanocrystalline TiO<sub>2</sub> solar cell has indicated a short circuit current of 0.252 mA, an open circuit potential of 377 mV with an overall efficiency of 3.63%. The overall conversion efficiency of the system remains stable for a long period due to the efficient electron injection into the conduction band during light absorption. The high resolution scanning electron microscopy picture reveals a three-dimensional network of interconnected nanoscale particles, while x-ray diffraction studies show that the particle size is 21 nm. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Копирайт | IOP Publishing Ltd |
| Название | 4′-functionalized 2,2′:6′,2′′ terpyridine ruthenium (II) complex: a nanocrystalline TiO<sub>2</sub> based solar cell sensitizer |
| Тип | paper |
| DOI | 10.1088/0957-4484/18/9/095701 |
| Electronic ISSN | 1361-6528 |
| Print ISSN | 0957-4484 |
| Журнал | Nanotechnology |
| Том | 18 |
| Первая страница | 95701 |
| Последняя страница | 95705 |
| Аффилиация | Anthonysamy, Arockiam; Department of Inorganic Chemistry, School of Chemical Sciences, University of Madras, Guindy Campus, Chennai-600 025, India |
| Аффилиация | Balasubramanian, Sengottuvelan; Department of Inorganic Chemistry, School of Chemical Sciences, University of Madras, Guindy Campus, Chennai-600 025, India ; |
| Аффилиация | Muthuraaman, Bhagavathiachari; Department of Energy, University of Madras, Guindy Campus, Chennai-600 025, India |
| Аффилиация | Maruthamuthu, Pichai; Department of Energy, University of Madras, Guindy Campus, Chennai-600 025, India |
| Выпуск | 9 |
