Автор |
Zhang, Hui |
Автор |
Wu, Jianbo |
Автор |
Zhai, Chuanxin |
Автор |
Ma, Xiangyang |
Автор |
Du, Ning |
Автор |
Tu, Jiangping |
Автор |
Yang, Deren |
Дата выпуска |
2008-01-23 |
dc.description |
We have developed a simple approach for the large-scale synthesis of cobalt nitrate carbonate hydroxide hydrate (Co(CO<sub>3</sub>)<sub>0.35</sub>(NO<sub>3</sub>)<sub>0.2</sub>(OH)<sub>1.1</sub>·1.74H<sub>2</sub>O) nanowires via the hydrothermal process using sodium hydroxide and formaldehyde as mineralizers at 120 °C. The porous Co<sub>3</sub>O<sub>4</sub> nanorods 10–30 nm in diameter and hundreds of nanometres in length have been fabricated from the above-mentioned multicomponent nanowires by calcination at 400 °C. The morphology and structure of cobalt nitrate carbonate hydroxide hydrate nanowires and Co<sub>3</sub>O<sub>4</sub> nanorods have been characterized by transmission electron microscopy (TEM), field emission scanning electron microscopy (FESEM), high resolution transmission electron microscopy (HRTEM) and x-ray powder diffraction (XRD). Moreover, the porous Co<sub>3</sub>O<sub>4</sub> nanorods have been applied in the negative electrode materials for lithium ion batteries, which exhibit high electrochemical performance. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Копирайт |
IOP Publishing Ltd |
Название |
From cobalt nitrate carbonate hydroxide hydrate nanowires to porous Co<sub>3</sub>O<sub>4</sub> nanorods for high performance lithium-ion battery electrodes |
Тип |
paper |
DOI |
10.1088/0957-4484/19/03/035711 |
Electronic ISSN |
1361-6528 |
Print ISSN |
0957-4484 |
Журнал |
Nanotechnology |
Том |
19 |
Первая страница |
35711 |
Последняя страница |
35715 |
Аффилиация |
Yang, Deren; |
Аффилиация |
Zhang, Hui; State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China |
Аффилиация |
Wu, Jianbo; State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China |
Аффилиация |
Zhai, Chuanxin; State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China |
Аффилиация |
Ma, Xiangyang; State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China |
Аффилиация |
Du, Ning; State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China |
Аффилиация |
Tu, Jiangping; State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China |
Выпуск |
3 |