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Автор Zhang, Hui
Автор Du, Ning
Автор Wu, Ping
Автор Chen, Bingdi
Автор Yang, Deren
Дата выпуска 2008-08-06
dc.description A novel approach has been developed to synthesize magnetic nanoparticle and carbon nanotube (CNT) core–shell nanostructures, such as CoO/CNTs and Mn<sub>3</sub>O<sub>4</sub>/CNTs, by the nonaqueous solvothermal treatment of metal carbonyl on CNT templates using hexane as the solvent. The morphological and structural characterizations indicate that numerous cubic CoO or tetragonal Mn<sub>3</sub>O<sub>4</sub> nanoparticles are deposited on the surfaces of the CNTs to form CNT-based core–shell nanostructures. It is revealed that the hydrophobic interaction between nanoparticles and CNTs in hexane plays the critical role for the formation of CNT-based core–shell nanostructures. A physical property measurement system (PPMS-9, Quantum Design) analysis indicates that the CoO/CNT core–shell nanostructures show weak ferromagnetic performance at 300 K due to the ferromagnetic Co clusters and the uncompensated surface spin states, while the Mn<sub>3</sub>O<sub>4</sub>/CNT core–shell nanostructures display ferromagnetic behavior at low temperature (34.5 K), which transforms into paramagnetic behavior with increasing temperature.
Формат application.pdf
Издатель Institute of Physics Publishing
Копирайт IOP Publishing Ltd
Название Functionalization of carbon nanotubes with magnetic nanoparticles: general nonaqueous synthesis and magnetic properties
Тип paper
DOI 10.1088/0957-4484/19/31/315604
Electronic ISSN 1361-6528
Print ISSN 0957-4484
Журнал Nanotechnology
Том 19
Первая страница 315604
Последняя страница 315609
Аффилиация Yang, Deren;
Аффилиация Zhang, Hui; State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Аффилиация Du, Ning; State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Аффилиация Wu, Ping; State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Аффилиация Chen, Bingdi; State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
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