Автор |
Zhang, Hui |
Автор |
Du, Ning |
Автор |
Wu, Ping |
Автор |
Chen, Bingdi |
Автор |
Yang, Deren |
Дата выпуска |
2008-08-06 |
dc.description |
A novel approach has been developed to synthesize magnetic nanoparticle and carbon nanotube (CNT) core–shell nanostructures, such as CoO/CNTs and Mn<sub>3</sub>O<sub>4</sub>/CNTs, by the nonaqueous solvothermal treatment of metal carbonyl on CNT templates using hexane as the solvent. The morphological and structural characterizations indicate that numerous cubic CoO or tetragonal Mn<sub>3</sub>O<sub>4</sub> nanoparticles are deposited on the surfaces of the CNTs to form CNT-based core–shell nanostructures. It is revealed that the hydrophobic interaction between nanoparticles and CNTs in hexane plays the critical role for the formation of CNT-based core–shell nanostructures. A physical property measurement system (PPMS-9, Quantum Design) analysis indicates that the CoO/CNT core–shell nanostructures show weak ferromagnetic performance at 300 K due to the ferromagnetic Co clusters and the uncompensated surface spin states, while the Mn<sub>3</sub>O<sub>4</sub>/CNT core–shell nanostructures display ferromagnetic behavior at low temperature (34.5 K), which transforms into paramagnetic behavior with increasing temperature. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Копирайт |
IOP Publishing Ltd |
Название |
Functionalization of carbon nanotubes with magnetic nanoparticles: general nonaqueous synthesis and magnetic properties |
Тип |
paper |
DOI |
10.1088/0957-4484/19/31/315604 |
Electronic ISSN |
1361-6528 |
Print ISSN |
0957-4484 |
Журнал |
Nanotechnology |
Том |
19 |
Первая страница |
315604 |
Последняя страница |
315609 |
Аффилиация |
Yang, Deren; |
Аффилиация |
Zhang, Hui; State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China |
Аффилиация |
Du, Ning; State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China |
Аффилиация |
Wu, Ping; State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China |
Аффилиация |
Chen, Bingdi; State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China |
Выпуск |
31 |