The 12th International Workshop on Plasma-Facing Materials and Components for Fusion Applications (PFMC-12) was held in Forschungszentrum Jülich (FZJ) in Germany in May 2009. This symposium is the successor to the International Workshop on Carbon Materials for Fusion Applications series. Between 1985 and 2003, 10 'Carbon Workshops' were organized in Jülich, Stockholm and Hohenkammer. After this time, the scope of the symposium was redefined to reflect the new requirements of ITER and the ongoing evolution of the field. The workshop was first organized under its new name in 2006 in Greifswald, Germany. The main objective of this conference series is to provide a discussion forum for experts from research institutions and industry dealing with materials for plasma-facing components in present and future controlled fusion devices. The operation of ASDEX-Upgrade with tungsten-coated wall, the fast progress of the ITER-Like Wall Project at JET, the plans for the EAST tokamak to install tungsten, the start of ITER construction and a discussion about the wall material for DEMO all emphasize the importance of plasma–wall interactions and component behaviour, and give much momentum to the field. In this context, the properties and behaviour of beryllium, carbon and tungsten under plasma impact are research topics of foremost relevance and importance. Our community realizes both the enormous advantages and serious drawbacks of all the candidate materials. As a result, discussion is in progress as to whether to use carbon in ITER during the initial phase of operation or to abandon this element and use only metal components from the start. There is broad knowledge about carbon, both in terms of its excellent power-handling capabilities and the drawbacks related to chemical reactivity with fuel species and, as a consequence, about problems arising from fuel inventory and dust formation. We are learning continuously about beryllium and tungsten under fusion conditions, but our knowledge is still limited, especially in relation to the behaviour of these metals in environments containing multiple species. There are many appealing issues related to material mixing and fuel retention that call for robust and comprehensive studies. In this sense, the aim of the workshop is not only to discuss hot topics, but also to identify the most important research areas and those that need urgent solutions. Another topic of foremost relevance to ITER is the development of plasma-facing components that are able to withstand extreme power fluxes, in particular, those during transient phases. Materials and production methods for high-heat-flux components have to be further developed and industrialized. A key requirement in this field is the development of non-destructive testing methods for the qualification of methods and quality assessment during production. Invited talks and contributed presentations therefore dealt with aspects of fundamental processes, experimental findings, advanced modelling and the technology of fusion reactor components.Several areas were selected as the major topics of PFMC-12:materials for the ITER-divertor (erosion, redeposition, fuel retention) carbon-based materials tungsten and tungsten coatings berylliummixed materials (intentional and non-intentional) the ITER-Like Wall Project materials under high-heat-flux loads including transients (ELMs, disruptions) technology and testing of plasma-facing components neutron effects in plasma-facing materials.26 invited lectures and oral contributions, and 131 posters were presented by participants from research laboratories and industrial companies. 210 researchers from 24 countries from all over the world participated in a lively and intense exchange of knowledge and ideas. The workshop was hosted by Forschungszentrum Jülich (FZJ), a centre where the integration of science and technology for fusion reactor materials has been a focus for decades. This is reflected by the operation of several devices vital for progress in fusion research. TEXTOR (Toroidal EXperiment for Technology Oriented Research) is a mission-oriented tokamak for the study of plasma–wall interactions and testing of materials in fusion environments. JUDITH-1 (JÜlich DIvertor Test facility in Hot-cell) and the recently started JUDITH-2 are the most powerful test beds for studies of material performance under steady-state or pulsed power loads. The results of testing in JUDITH establish the background for material qualification. The expertize of FZJ in fusion engineering is vital for the construction of the Wendelstein-7X stellarator in Greifswald and the diagnostics for the ITER plasma. Finally, there is a group of eminent theoreticians and modellers at work in FZJ. As a consequence, FZJ is the home of the supercomputer, High Performance Computing-For Fusion (HPC-FF). During the workshop, special guided laboratory tours were organized to get the participants acquainted with the experimental facilities at FZJ: TEXTOR, JUDITH and HPC-FF.The quality of the talks, posters and discussions, and the comfortable conference facilities were of great importance but activities outside fusion science also formed part of the workshop. A guided tour in the Old Town of Aachen was very much appreciated by all participants; a stroll in this beautiful place was not only a relaxing moment but also put participants in touch with a great deal of European history.Big and long-term projects always attract young, ambitious people. The recruitment of talented scientists is a conditio sine qua non for the future success and progress of fusion science and engineering. The enthusiasm of students is very important but not sufficient; it is the responsibility of older colleagues to get students acquainted with the major issues and challenges. For this reason, the workshop was preceded by a series of tutorials on plasma–wall interactions and properties, and testing of relevant materials. The lectures were met with a great response: not only did over thirty young colleagues register but also senior scientists registered for the course and were very active in discussions.The workshop was supported financially by Forschungszentrum Jülich and the ExtreMat Integrated Project, a programme for the development and study of new materials for extreme environments. We are very grateful to the staff of Forschungszentrum who helped with the organization. Our most cordial thanks and gratitude go to Yasmin Fattah, Angelika Hallmanns, Gabriele Knauf and Gerd Boeling for all their kindness and efficiency, which helped all of us to enjoy the meeting.We thank most sincerely our colleagues Gerald Pintsuk, Takeshi Hirai and Andrey Litnovsky for their most professional work in the construction and operation of the conference webpage, the preparation of the sessions and for all other elements that were vital for the smooth running of the meeting. We thank very much Marliese Felden and Ralf-Uwe Limbach who very kindly and professionally took care of the photographic documentation of the workshop.The proceedings of this workshop contains 67 peer-reviewed articles covering the contents of most of the invited presentations and a number of poster contributions which were pre-selected by the programme committee. The papers reflect the development and actual status of the field. We thank all participants for their contributions and the referees for their smooth and efficient peer-review. Thank you all for your hard work and co-operation. We are looking forward to seeing you at the next meeting; we invite you to come, though we are not yet able to say 'when' and 'where' we will meet next time. It is a special feature of this conference series that a new meeting is announced only when the community feels that there is substantial new material to be presented and discussed.