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Автор M A Islam
Дата выпуска 2004-01-01
dc.description Two forms of diffusion equation are discussed: (1) the conventional Fick’s law with concentration-independent diffusion coefficient and (2) the flux as proportional to the chemical potential gradient with the proportional constant independent of concentration (which is, in most cases, equivalent to the application of Fick’s law with a diffusion coefficient inversely proportional to concentration). It is shown that appropriate empirical form of the resistant forces could validate both forms thermodynamically. It is concluded that the ideal form of diffusion equation is absent. It is also shown that the second form of the flux equation might describe the self-diffusion flux better.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Fickian Diffusion Equation—an Unsolved Problem
Тип paper
DOI 10.1088/0031-8949/70/2-3/007
Electronic ISSN 1402-4896
Print ISSN 0031-8949
Журнал Physica Scripta
Том 70
Первая страница 114
Последняя страница 119
Аффилиация M A Islam; GKSS Forschungszentrum Geesthacht GmbH, Kantstrasse 55, Teltow, D-14513, Germany
Выпуск 2-3

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