Ammonium nitrate melt technique for the synthesis of oxide compounds
Ugur Topal; Ugur Topal; Tubitak-UME, P.K.54, 41470 Gebze-KOCAELI/Turkey
Журнал:
Journal of Physics: Conference Series
Дата:
2009-03-01
Аннотация:
In this study, we propose a wet chemical method, called ammonium-nitrate-melt-technique, for the synthesis of any type of bulk oxide compounds. This method was successfully applied to the high-T<sub>c</sub> superconductors (Y-123, Ru-2212, etc), diluted magnetic semiconductors (Ti<sub>1-x</sub>CoO<sub>2</sub>) and hard magnetic barium ferrites (BaFe<sub>12</sub>O<sub>19</sub>). For instance, we have obtained a single phase M-type barium ferrites with finely granular structure at nanoscale (300-400 nm). Magnetic parameters of these samples are near to the theoretically estimated values. Besides, superconducting transition temperature of ∼70 K was observed in ferromagnetism&superconductivity co-existed ruthenates, which is only possible at very high oxygination pressures (600 atm). Consequently, we believe that the method will attract the attention of many material scientists.
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