| Автор | Maria Miheţ |
| Автор | Mihaela Lazar |
| Автор | Valer Almăşan |
| Дата выпуска | 2009-08-01 |
| dc.description | A previously developed theoretical model has been used to evaluate metal to support transport rate coefficients of spilt over hydrogen species in case of Ni supported catalysts. Four Ni/oxide (Ni/Cr<sub>2</sub>O<sub>3</sub>, Ni/ZrO<sub>2</sub>, Ni/SiO<sub>2</sub>, and Ni/MgO) catalysts were investigated by isotopic transient kinetic method for H/D exchange reaction. A good agreement between experimental data and theoretical ones has been put into evidence, both cases showing an important influence of oxide nature on the quantity of spilt over hydrogen. Fitting the experimental with the calculated theoretical data permitted the evaluation of transport rate coefficients from the spillover initiator (metal) to the acceptor of migrating species (the oxide support). |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Копирайт | © 2009 IOP Publishing Ltd |
| Название | Mobility of hydrogen species on Ni supported catalysts |
| Тип | paper |
| DOI | 10.1088/1742-6596/182/1/012051 |
| Electronic ISSN | 1742-6596 |
| Print ISSN | 1742-6588 |
| Журнал | Journal of Physics: Conference Series |
| Том | 182 |
| Первая страница | 12051 |
| Последняя страница | 12054 |
| Аффилиация | Maria Miheţ; National Institute for Research and Development of Isotopic and Molecular Technologies, 65–103 Donath, 400293 Cluj-Napoca, Romania |
| Аффилиация | Mihaela Lazar; National Institute for Research and Development of Isotopic and Molecular Technologies, 65–103 Donath, 400293 Cluj-Napoca, Romania |
| Аффилиация | Valer Almăşan; National Institute for Research and Development of Isotopic and Molecular Technologies, 65–103 Donath, 400293 Cluj-Napoca, Romania |
| Выпуск | 1 |
