Автор |
J L Lapka |
Автор |
A Paulenova |
Автор |
L N Zakharov |
Автор |
M Yu Alyapyshev |
Автор |
V A Babain |
Дата выпуска |
2010-03-01 |
dc.description |
Structural analyses of uranyl complexes with isomers of N,N'-diethyl-N,N'-ditolyl-dipicolinamide were carried out using IR spectroscopy and single crystal x-ray diffraction. From these analyses it was determined that complexation takes place through coordination with the carbonyl and pyridine nitrogen moieties. The uranium-oxygen and uranium-nitrogen bond distances for Et(p)TDPA are U(1)-O(1): 2.394(3), U(1)-O(2): 2.460(3), U(1)-N(1): 2.661(3) and for Et(o)TDPA U(1)-O(1): 2.415(5), U(1)-O(2): 2.432(4), and U(1)-N(1): 2.647(5). |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Копирайт |
© 2010 IOP Publishing Ltd |
Название |
Coordination of uranium(VI) with N,N'-diethyl-N,N'-ditolyldipicolinamide |
Тип |
paper |
DOI |
10.1088/1757-899X/9/1/012029 |
Electronic ISSN |
1757-899X |
Print ISSN |
1757-8981 |
Журнал |
IOP Conference Series: Materials Science and Engineering |
Том |
9 |
Первая страница |
12029 |
Последняя страница |
12035 |
Выпуск |
1 |