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Автор Van-Pham, Dan-Thuy
Автор Trinh, Xuan-Anh
Автор Nakanishi, Hideyuki
Автор Tran-Cong-Miyata, Qui
Дата выпуска 2010-03-01
dc.description Phase separation of polymer mixtures is induced and controlled by photo-cross-link and photopolymerization using ultraviolet (UV) light. By taking advantage of the competition between phase separation and chemical reactions, a variety of morphologies such as co-continuous, spatially graded co-continuous and periodic structures with controllable periods, and hexagonal structures, etc, are obtained experimentally. The reaction kinetics (photo-cross-link or photopolymerization), reaction-induced elastic strain and phase separation kinetics are monitored, respectively, by UV–Vis spectroscopy, FTIR, Mach–Zehnder interferometry (MZI), light scattering (LS) and laser-scanning confocal microscopy (LSCM). Spatial modulation of light intensity generated by computer-assisted irradiation (CAI) is also used to induce phase separation of polymer blends. The correlation between the reaction-induced phase separation of polymer mixtures and the competing interactions is discussed with some perspectives on designing polymer materials with high performance.
Формат application.pdf
Издатель Institute of Physics Publishing
Копирайт 2010 Vietnam Academy of Science & Technology
Название Design and morphology control of polymer nanocomposites using light-driven phase separation phenomena
Тип rev
DOI 10.1088/2043-6254/1/1/013002
Electronic ISSN 2043-6262
Print ISSN 2043-6254
Журнал Advances in Natural Sciences: Nanoscience and Nanotechnology
Том 1
Первая страница 13002
Последняя страница 13012
Аффилиация Van-Pham, Dan-Thuy; Department of Macromolecular Science and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Matsugasaki, Kyoto 606-8585, Japan
Аффилиация Trinh, Xuan-Anh; International Training Institute for Materials Science (ITIMS), Hanoi University of Technology, 1 Dai Co Viet Road, Hanoi, Vietnam
Аффилиация Nakanishi, Hideyuki; Department of Macromolecular Science and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Matsugasaki, Kyoto 606-8585, Japan
Аффилиация Tran-Cong-Miyata, Qui; Department of Macromolecular Science and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Matsugasaki, Kyoto 606-8585, Japan
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